Basal-Plane Functionalization of Chemically Exfoliated Molybdenum Disulfide by Diazonium Salts
نویسندگان
چکیده
منابع مشابه
Functionalization of carbon nanotubes by electrochemical reduction of aryl diazonium salts: a bucky paper electrode.
Small-diameter (ca. 0.7 nm) single-wall carbon nanotubes are predicted to display enhanced reactivity relative to larger-diameter nanotubes due to increased curvature strain. The derivatization of these small-diameter nanotubes via electrochemical reduction of a variety of aryl diazonium salts is described. The estimated degree of functionalization is as high as one out of every 20 carbons in t...
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The production of two-dimensional rhenium disulfide (ReS2) nanosheets by exfoliation using lithium intercalation is demonstrated. The vibrational and photoluminescence properties of the exfoliated nanosheets are investigated, and the local atomic structure is studied by scanning and transmission electron microscopy. The catalytic activity of the nanosheets in a hydrogen evolution reaction (HER)...
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We report on the electrochemical charge storage behavior of few-layered flakes of molybdenum disulfide (MoS2) obtained by liquid phase exfoliation of bulk MoS2 powder in 1-dodecyl-2-pyrrolidinone. The specific capacitances of the exfoliated flakes obtained using a 6 M KOH aqueous solution as an electrolyte were found to be an order of magnitude higher than those of bulk MoS2 (∼0.5 and ∼2 mF cm(...
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ژورنال
عنوان ژورنال: ACS Nano
سال: 2015
ISSN: 1936-0851,1936-086X
DOI: 10.1021/acsnano.5b00965